A new Lewis-base ionic liquid comprising a mono-charged diamine structure: A highly stable electrolyte for lithium electrochemistry

被引：53

作者：

Yoshizawa-Fujita, M

MacFarlane, DR

Howlett, PC

Forsyth, M

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2006年 / 8卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

ionic liquid; Lewis base; lithium electrochemistry; ionic conductivity;

D O I：

10.1016/j.elecom.2006.01.008

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new Lewis-base ionic liquid (IL) based on mono-charged 1,4-diazabicyclo[2.2.2]octane (dabco) was synthesized and its thermal and electrochemical behaviour was characterized. The dabco-based IL with bis(trifluoromethanesulfonyl)amide (TFSA) anion melts at 76 degrees C when the N-substituted alkyl chain length is 2. The dabco-based IL showed a wide electrochemical window of over 4 V ranging from -3.5 to +1.5 V vs. Fc/Fc(+) and was able to deposit and strip lithium from a nickel substrate at reasonable efficiency. (c) 2006 Elsevier B.V. All rights reserved.

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页码：445 / 449

页数：5

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