Photochemical and Photoelectrochemical Reduction of CO2

被引：912

作者：

Kumar, Bhupendra ^{[1
]}

Llorente, Mark ^{[1
]}

Froehlich, Jesse ^{[2
]}

Dang, Tram ^{[1
]}

Sathrum, Aaron ^{[1
]}

Kubiak, Clifford P. ^{[1
,2
]}

机构：

[1] Univ Calif San Diego, Mat Sci & Engn Program, La Jolla, CA 92093 USA

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 63 | 2012年 / 63卷

关键词：

solar fuels; molecular catalyst; photocathode; semiconductor/catalyst junction; homogeneous catalysis; heterogeneous catalysis; P-TYPE SILICON; INDIUM-PHOSPHIDE ELECTRODES; AQUEOUS CARBON-DIOXIDE; PARA-GALLIUM ARSENIDE; HIGH-PRESSURE CO2; ELECTROCHEMICAL REDUCTION; ELECTROCATALYTIC REDUCTION; SEMICONDUCTOR-LIQUID; PHOTOELECTROCATALYTIC REDUCTION; CATALYZED PHOTOREDUCTION;

D O I：

10.1146/annurev-physchem-032511-143759

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The recent literature on photochemical and photoelectrochemical reductions of CO2 is reviewed. The different methods of achieving light absorption, electron-hole separation, and electrochemical reduction of CO2 are considered. Energy gap matching for reduction of CO2 to different products, including CO, formic acid, and methanol, is used to identify the most promising systems. Different approaches to lowering overpotentials and achieving high chemical selectivities by employing catalysts are described and compared.

引用

页码：541 / +

页数：54

共 173 条

[1] Reduction catalysis by metal complexes confined in a polymer matrix
Abe, T
Kaneko, M
[J]. PROGRESS IN POLYMER SCIENCE, 2003, 28 (10) : 1441 - 1488
[2] Factors affecting selective electrocatalytic CO2 reduction with cobalt phthalocyanine incorporated in a polyvinylpyridine membrane coated on a graphite electrode
Abe, T
Yoshida, T
Tokita, S
Taguchi, F
Imaya, H
Kaneko, M
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 412 (1-2): : 125 - 132
[3] Heterogenous Catalysis Mediated by Plasmon Heating
Adleman, James R.
Boyd, David A.
Goodwin, David G.
Psaltis, Demetri
[J]. NANO LETTERS, 2009, 9 (12) : 4417 - 4423
[4] Reduction of CO2 on a Tricarbonyl Rhenium(I) Complex: Modeling a Catalytic Cycle
Agarwal, Jay
Johnson, Richard P.
Li, Gonghu
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (13) : 2877 - 2881
[5] MECHANISM AND KINETIC CHARACTERISTICS OF THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE IN MEDIA OF LOW PROTON AVAILABILITY
AMATORE, C
SAVEANT, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (17) : 5021 - 5023
[6] Covalent Attachment of a Rhenium Bipyridyl CO2 Reduction Catalyst to Rutile TiO2
Anfuso, Chantelle L.
Snoeberger, Robert C., III
Ricks, Allen M.
Liu, Weimin
Xiao, Dequan
Batista, Victor S.
Lian, Tianquan
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (18) : 6922 - 6925
[7] Photoelectrochemical reduction of CO2 in water under visible-light irradiation by a p-type InP photocathode modified with an electropolymerized ruthenium complex
Arai, Takeo
Sato, Shunsuke
Uemura, Keiko
Morikawa, Takeshi
Kajino, Tsutomu
Motohiro, Tomoyoshi
[J]. CHEMICAL COMMUNICATIONS, 2010, 46 (37) : 6944 - 6946
[8] A method for optimal sizing of an electrolyzer directly connected to a PV module
Atlam, Ozcan
Barbir, Frano
Bezmalinovic, Dario
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (12) : 7012 - 7018
[9] Aurian-Blajeni B, SOLAR ENERGY MAT, V8, P425
[10] ELECTROCHEMICAL MEASUREMENTS ON THE PHOTO-ELECTROCHEMICAL REDUCTION OF AQUEOUS CARBON-DIOXIDE ON PARA-GALLIUM PHOSPHIDE AND PARA-GALLIUM ARSENIDE SEMICONDUCTOR ELECTRODES
AURIANBLAJENI, B
HALMANN, M
MANASSEN, J
[J]. SOLAR ENERGY MATERIALS, 1983, 8 (04): : 425 - 440

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