Zipping up 'the crushed fullerene' C60H30:: C60 by fifteen-fold, consecutive intramolecular H2 losses

被引：26

作者：

Gómez-Lor, B

Koper, C

Fokkens, RH

Vlietstra, EJ

Cleij, TJ

Jenneskens, LW

Nibbering, NMM

Echavarren, AM

机构：

[1] Univ Utrecht, Debye Inst, Dept Phys Organ Chem, NL-3584 CH Utrecht, Netherlands

[2] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

[3] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain

[4] Univ Twente, MESA Res Inst, NL-7500 AE Enschede, Netherlands

[5] Vrije Univ Amsterdam, Ctr Laser, NL-1081 HV Amsterdam, Netherlands

[6] Vrije Univ Amsterdam, Dept Chem, NL-1081 HV Amsterdam, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 04期

关键词：

D O I：

10.1039/b110587f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MALDI TOF-MS of tribenzo[l:l':l"]benzo[1,2-e:3,4-e':5,6-e"]triacephenanthrylene (1a, C60H30) gives C60.+ by multiple intramolecular cyclodehydrogenation reactions.

引用

页码：370 / 371

页数：2

共 26 条

[1] Groundwork for a rational synthesis of C60:: Cyclodehydrogenation of a C60H30 polyarene [J].

Boorum, MM ;

Vasil'ev, YV ;

Drewello, T ;

Scott, LT .

SCIENCE, 2001, 294 (5543) :828-831

[2] Energetics and site specificity of the homolytic C-H bond cleavage in benzenoid hydrocarbons: An ab initio electronic structure study [J].

Cioslowski, J ;

Liu, GH ;

Martinov, M ;

Piskorz, P ;

Moncrieff, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (22) :5261-5264

[3]

de Frutos O, 1999, ANGEW CHEM INT EDIT, V38, P204, DOI 10.1002/(SICI)1521-3773(19990115)38:1/2<204::AID-ANIE204>3.0.CO

[4]

2-5

[5] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[6] Photodissociation of gas-phase polycylic aromatic hydrocarbon cations [J].

Ekern, SP ;

Marshall, AG ;

Szczepanski, J ;

Vala, M .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (20) :3498-3504

[7] Synthesis of 'crushed fullerene' C60H30 [J].

Gómez-Lor, B ;

de Frutos, O ;

Echavarren, AM .

CHEMICAL COMMUNICATIONS, 1999, (23) :2431-2432

[8]

Hirsch A, 1999, TOP CURR CHEM, V199, P1

[9] SOLID C-60 - A NEW FORM OF CARBON [J].

KRATSCHMER, W ;

LAMB, LD ;

FOSTIROPOULOS, K ;

HUFFMAN, DR .

NATURE, 1990, 347 (6291) :354-358

[10] C-60 - BUCKMINSTERFULLERENE [J].

KROTO, HW ;

HEATH, JR ;

OBRIEN, SC ;

CURL, RF ;

SMALLEY, RE .

NATURE, 1985, 318 (6042) :162-163

← 1 2 3 →