Preparation of gold/polyaniline/multiwall carbon nanotube nanocomposites and application in ammonia gas detection

被引:64
作者
Chang, Qifei [1 ,2 ]
Zhao, Kai [1 ]
Chen, Xing [1 ]
Li, Minqiang [1 ]
Liu, Jinhuai [1 ]
机构
[1] Chinese Acad Sci, Inst Intelligent Machines, Key Lab Biomimet Sensing & Adv Robot Technol, Hefei 230031, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1007/s10853-008-2827-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Composites of multiwall carbon nanotubes (MWNTs), polyaniline (PANI), and gold nanoparticles were prepared by one pot synthesis. Based on the interaction between aniline monomers and MWNTs, aniline molecules were adsorbed and polymerized on the surface of MWNTs. The nanocomposites were characterized by transmission electron microscopy (TEM), X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoemission spectroscopy (XPS). The sensors based on Au/PANI/MWNT nanocomposites were tested for on-line monitoring of ammonia gas. The results show that the as-prepared sensors have superior sensitivity, and good repeatability upon repeated exposure to ammonia gas.
引用
收藏
页码:5861 / 5866
页数:6
相关论文
共 35 条
[21]   Synthesis and characterization of hydrophobic, organically-soluble gold nanocrystals functionalized with primary amines [J].
Leff, DV ;
Brandt, L ;
Heath, JR .
LANGMUIR, 1996, 12 (20) :4723-4730
[22]   Carbon nanotube sensors for gas and organic vapor detection [J].
Li, J ;
Lu, YJ ;
Ye, Q ;
Cinke, M ;
Han, J ;
Meyyappan, M .
NANO LETTERS, 2003, 3 (07) :929-933
[23]   Polymeric nanowire chemical sensor [J].
Liu, HQ ;
Kameoka, J ;
Czaplewski, DA ;
Craighead, HG .
NANO LETTERS, 2004, 4 (04) :671-675
[24]   Self-assembly of mesoscopically ordered chromatic polydiacetylene/silica nanocomposites [J].
Lu, YF ;
Yang, Y ;
Sellinger, A ;
Lu, MC ;
Huang, JM ;
Fan, HY ;
Haddad, R ;
Lopez, G ;
Burns, AR ;
Sasaki, DY ;
Shelnutt, J ;
Brinker, CJ .
NATURE, 2001, 410 (6831) :913-917
[25]   Materials science - Putting metals into polymers [J].
Manners, I .
SCIENCE, 2001, 294 (5547) :1664-1666
[26]   Miniaturized gas ionization sensors using carbon nanotubes [J].
Modi, A ;
Koratkar, N ;
Lass, E ;
Wei, BQ ;
Ajayan, PM .
NATURE, 2003, 424 (6945) :171-174
[27]  
MOON YB, 1989, POLYM COMMUN, V30, P196
[28]   Controllable Pt nanoparticle deposition on carbon nanotubes as an anode catalyst for direct methanol fuel cells [J].
Mu, YY ;
Liang, HP ;
Hu, JS ;
Jiang, L ;
Wan, LJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (47) :22212-22216
[29]   Cr2O3-activated ZnO thick film resistors for ammonia gas sensing operable at room temperature [J].
Patil, D. R. ;
Patil, L. A. ;
Patil, P. P. .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 126 (02) :368-374
[30]   Alcohol detection using carbon nanotubes acoustic and optical sensors [J].
Penza, M ;
Cassano, G ;
Aversa, P ;
Antolini, F ;
Cusano, A ;
Cutolo, A ;
Giordano, M ;
Nicolais, L .
APPLIED PHYSICS LETTERS, 2004, 85 (12) :2379-2381