Soft nanotechnology with soft nanoparticles

被引:707
作者
Nayak, S [1 ]
Lyon, LA [1 ]
机构
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
关键词
hydrogels; materials science; nanostructures; polymers; self-assembly;
D O I
10.1002/anie.200501321
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The last decade of research in the physical sciences has seen a dramatic increase in the study of nanoscale materials. Today, "nanoscience" has emerged as a multidisciplinary effort, wherein obtaining a fundamental understanding of the optical, electrical, magnetic, and mechanical properties of nanostructures promises to deliver the next generation of functional materials for a wide range of applications. While this range of efforts is extremely broad, much of the work has focused on "hard" materials, such as Buckyballs, carbon nanotubes, metals, semiconductors, and organic or inorganic dielectrics. Meanwhile, the soft materials of current interest typically include conducting or emissive polymers for "plastic electronics" applications. Despite the continued interest in these established areas of nanoscience, new classes of soft nanomaterials are being developed from more traditional polymeric constructs. Specifically, nanostructured hydrogels are emerging as a promising group of materials for multiple biotechnology applications as the need for advanced materials in the post-genomic era grows. This review will present some of the recent advances in the marriage between water-swellable networks and nanoscience. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7686 / 7708
页数:23
相关论文
共 225 条
[11]   Doubly temperature sensitive core-shell microgels [J].
Berndt, I ;
Richtering, W .
MACROMOLECULES, 2003, 36 (23) :8780-8785
[12]   Structure of multiresponsive "intelligent" core-shell microgels [J].
Berndt, I ;
Pedersen, JS ;
Richtering, W .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (26) :9372-9373
[13]   Galactosylated poly(N-isopropylacrylamide) hydrogel submicrometer particles for specific cellular uptake within hepatocytes [J].
Choi, SH ;
Yoon, JJ ;
Park, TG .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 251 (01) :57-63
[14]   Swelling behavior of poly N-isopropylacrylamide microgel particles in alcoholic solutions [J].
Crowther, HM ;
Vincent, B .
COLLOID AND POLYMER SCIENCE, 1998, 276 (01) :46-51
[15]   Hollow fiber-supported hydrogels with mesh-size asymmetry [J].
Dai, WS ;
Barbari, TA .
JOURNAL OF MEMBRANE SCIENCE, 2000, 171 (01) :79-86
[16]   Temperature-dependent electrophoretic mobility and hydrodynamic radius measurements of poly(N-isopropylacrylamide) microgel particles:: structural insights [J].
Daly, E ;
Saunders, BR .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (14) :3187-3193
[17]   Thermoresponsive photonic crystals [J].
Debord, JD ;
Lyon, LA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (27) :6327-6331
[18]  
Debord JD, 2002, ADV MATER, V14, P658, DOI 10.1002/1521-4095(20020503)14:9<658::AID-ADMA658>3.0.CO
[19]  
2-3
[20]   Influence of particle volume fraction on packing in responsive hydrogel colloidal crystals [J].
Debord, SB ;
Lyon, LA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (13) :2927-2932