Catalytic asymmetric Michael reactions promoted by the La-Na-BINOL complex (LSB). Enantioface selection on Michael donors

被引：95

作者：

Sasai, H ^{[1
]}

Emori, E ^{[1
]}

Arai, T ^{[1
]}

Shibasaki, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 31期

关键词：

D O I：

10.1016/0040-4039(96)01156-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

LSB can efficiently promote catalytic asymmetric Michael reactions in CH2Cl2, inducing high enantiomeric excesses on the Micheal donor side. The multifunctional character of LSB appears to give rise to high stereoselectivity, offering the most efficient asymmetric reaction of its type. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5561 / 5564

页数：4

共 27 条

[1] AOKI S, 1992, HETEROCYCLES, V33, P493
[2] SIMPLE CHIRAL CROWN ETHERS COMPLEXED WITH POTASSIUM TERT-BUTOXIDE AS EFFICIENT CATALYSTS FOR ASYMMETRIC MICHAEL ADDITIONS
AOKI, S
SASAKI, S
KOGA, K
[J]. TETRAHEDRON LETTERS, 1989, 30 (51) : 7229 - 7230
[3] A new multifunctional heterobimetallic asymmetric catalyst for Michael additions and tandem Michael-Aldol reactions
Arai, T
Sasai, H
Aoe, K
Okamura, K
Date, T
Shibasaki, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (01): : 104 - 106
[4] ASYMMETRIC CATALYSIS .18. ENANTIOSELECTIVE MICHAEL ADDITIONS WITH OPTICALLY-ACTIVE COII/DIAMINE CATALYSTS
BRUNNER, H
HAMMER, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (04): : 312 - 313
[5] CHIRAL CROWN COMPLEXES CATALYZE MICHAEL ADDITION-REACTIONS TO GIVE ADDUCTS IN HIGH OPTICAL YIELDS
CRAM, DJ
SOGAH, GDY
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (13) : 625 - 628
[6] COPPER(II) IN ORGANIC-SYNTHESIS .11. EVALUATION DF THE LIGAND ARCHITECTURE ON THE EFFICIENCY OF A COPPER(II) CATALYST FOR ENANTIOSELECTIVE MICHAEL REACTIONS
DESIMONI, G
DUSI, G
FAITA, G
QUADRELLI, P
RIGHETTI, P
[J]. TETRAHEDRON, 1995, 51 (14) : 4131 - 4144
[7] HELDER R, 1975, TETRAHEDRON LETT, P4057
[8] ASYMMETRIC INDUCTION IN THE MICHAEL REACTION
HERMANN, K
WYNBERG, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (13) : 2238 - 2244
[9] AN ENANTIOSELECTIVE MICHAEL ADDITION OF SOFT NUCLEOPHILES TO PROCHIRAL ENONE CATALYZED BY (2-PYRROLIDYL)ALKYL AMMONIUM HYDROXIDE
KAWARA, A
TAGUCHI, T
[J]. TETRAHEDRON LETTERS, 1994, 35 (47) : 8805 - 8808
[10] SYNTHESES OF (S)-(-)-PINDOLOL AND [3'-C-13]-(R)-(-)-PINDOLOL UTILIZING A LANTHANUM-TITHIUM-(R)-BINOL ((R)-LLB) CATALYZED NITROALDOL REACTION
SASAI, H
YAMADA, YMA
SUZUKI, T
SHIBASAKI, M
[J]. TETRAHEDRON, 1994, 50 (43) : 12313 - 12318

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