Nanostructure Engineering and Doping of Conjugated Carbon Nitride Semiconductors for Hydrogen Photosynthesis

被引：785

作者：

Lin, Zhenzhen ^{[1
,2
]}

Wang, Xinchen ^{[1
,2
]}

机构：

[1] Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base, Fuzhou 350002, Peoples R China

[2] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 06期

基金：

中国国家自然科学基金;

关键词：

carbon nitride; conjugated polymers; doping; nanosheets; photosynthesis; FRUSTRATED LEWIS PAIRS; POLYMERS; BORON; ACTIVATION; EVOLUTION; OXIDATION; GRAPHENE;

D O I：

10.1002/anie.201209017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Going flat out: Simultaneous modifications of the textural, surface, and electronic structures of a rigid conjugated carbon nitride polymer has been achieved using direct co-condensation of urea and Ph4BNa. This method gives boron-doped carbon nitride nanosheets (see picture) that optimize the capture of light, improve the charge-separation kinetics, and enhance the surface reactivity for hydrogen photosynthesis. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1735 / 1738

页数：4

共 59 条

[51] A Facile Band Alignment of Polymeric Carbon Nitride Semiconductors to Construct Isotype Heterojunctions [J].

Zhang, Jinshui ;

Zhang, Mingwen ;

Sun, Rui-Qing ;

Wang, Xinchen .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (40) :10145-10149

[52] Co-Monomer Control of Carbon Nitride Semiconductors to Optimize Hydrogen Evolution with Visible Light [J].

Zhang, Jinshui ;

Zhang, Guigang ;

Chen, Xiufang ;

Lin, Sen ;

Moehlmann, Lennart ;

Dolega, Grzegorz ;

Lipner, Grzegorz ;

Antonietti, Markus ;

Blechert, Siegfried ;

Wang, Xinchen .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (13) :3183-3187

[53] Sulfur-mediated synthesis of carbon nitride: Band-gap engineering and improved functions for photocatalysis [J].

Zhang, Jinshui ;

Sun, Jianhua ;

Maeda, Kazuhiko ;

Domen, Kazunari ;

Liu, Ping ;

Antonietti, Markus ;

Fu, Xianzhi ;

Wang, Xinchen .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (03) :675-678

[54] Synthesis of a Carbon Nitride Structure for Visible-Light Catalysis by Copolymerization [J].

Zhang, Jinshui ;

Chen, Xiufang ;

Takanabe, Kazuhiro ;

Maeda, Kazuhiko ;

Domen, Kazunari ;

Epping, Jan Dirk ;

Fu, Xianzhi ;

Antonietti, Markus ;

Wang, Xinchen .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (02) :441-444

[55] Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation [J].

Zhang, Yuanjian ;

Mori, Toshiyuki ;

Ye, Jinhua ;

Antonietti, Markus .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (18) :6294-+

[56] Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments [J].

Zhang, Yuanjian ;

Thomas, Arne ;

Antonietti, Markus ;

Wang, Xinchen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :50-+

[57] Highly Soluble Heteroheptacene: A New Building Block for p-Type Semiconducting Polymers [J].

Zheng, Qingdong ;

Chen, Shanci ;

Zhang, Bo ;

Wang, Lixin ;

Tang, Changquan ;

Katz, Howard E. .

ORGANIC LETTERS, 2011, 13 (02) :324-327

[58] Rational Design of High Performance Conjugated Polymers for Organic Solar Cells [J].

Zhou, Huaxing ;

Yang, Liqiang ;

You, Wei .

MACROMOLECULES, 2012, 45 (02) :607-632

[59] A Superacid-Catalyzed Synthesis of Porous Membranes Based on Triazine Frameworks for CO2 Separation [J].

Zhu, Xiang ;

Tian, Chengcheng ;

Mahurin, Shannon M. ;

Chai, Song-Hai ;

Wang, Congmin ;

Brown, Suree ;

Veith, Gabriel M. ;

Luo, Huimin ;

Liu, Honglai ;

Dai, Sheng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (25) :10478-10484

← 1 2 3 4 5 6 →