Stereoselective total synthesis of (+)-boronolide

被引：31

作者：

Boruwa, J ^{[1
]}

Barua, NC ^{[1
]}

机构：

[1] CSIR, Nat Prod Chem Div, Reg Res Lab, Jorhat 785006, Assam, India

来源：

TETRAHEDRON | 2006年 / 62卷 / 06期

关键词：

boronolide; asymmetric dihydroxylation; asymmetric Henry reaction; chiral allylation; Nef reaction; ring closing metathesis;

D O I：

10.1016/j.tet.2005.10.070

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A seteroselective total synthesis of (+)-boronolide is described. The key steps are Sharpless asymmetric dihydroxylation, Shibasaki's asymmetric Henry reaction, asymmetric allylation and ring closing metathesis. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1193 / 1198

页数：6

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