Theory of substitueut effects:: Recent advances

被引：108

作者：

Exner, O

Böhm, S

机构：

[1] Prague Inst Chem Technol, Dept Organ Chem, CR-16628 Prague 6, Czech Republic

[2] Acad Sci Czech Republ, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic

来源：

CURRENT ORGANIC CHEMISTRY | 2006年 / 10卷 / 07期

关键词：

D O I：

10.2174/138527206776818892

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The review reports recent progress in the studies of substituent effects in isolated molecules, i.e. based either oil the experimental gas-phase acidities (basicities), or on quantum chemical calculations. Attention was focused on cases when the results differed from or exceeded the traditional views: redefinition of the inductive effect, quantitative estimation of resonance., validity of the Hammett equation, interpretation of the ortho effect, additivity of the enthalpies of formation, acidity of carboxylic acids.

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页码：763 / 778

页数：16

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