Theory of substitueut effects:: Recent advances

被引：108

作者：

Exner, O

Böhm, S

机构：

[1] Prague Inst Chem Technol, Dept Organ Chem, CR-16628 Prague 6, Czech Republic

[2] Acad Sci Czech Republ, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic

来源：

CURRENT ORGANIC CHEMISTRY | 2006年 / 10卷 / 07期

关键词：

D O I：

10.2174/138527206776818892

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The review reports recent progress in the studies of substituent effects in isolated molecules, i.e. based either oil the experimental gas-phase acidities (basicities), or on quantum chemical calculations. Attention was focused on cases when the results differed from or exceeded the traditional views: redefinition of the inductive effect, quantitative estimation of resonance., validity of the Hammett equation, interpretation of the ortho effect, additivity of the enthalpies of formation, acidity of carboxylic acids.

引用

页码：763 / 778

页数：16

共 152 条

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