Determination of chemical diffusion coefficient of SrFeCo0.5Ox by the conductivity relaxation method

被引：85

作者：

Ma, B ^{[1
]}

Balachandran, U ^{[1
]}

Park, JH ^{[1
]}

Segre, CU ^{[1
]}

机构：

[1] IIT,DEPT PHYS,CHICAGO,IL 60616

来源：

SOLID STATE IONICS | 1996年 / 83卷 / 1-2期

关键词：

diffusion; strontium-iron-cobalt-oxide systems; conductivity relaxation;

D O I：

10.1016/0167-2738(95)00227-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A conductivity relaxation experiment has been conducted on an SrFeCo0.5Ox sample by abruptly changing the oxygen partial pressure in the atmosphere and monitoring the change of conductivity as a function of time. The re-equilibrium process obeys Fick's second law. By fitting the relaxation data to the solution of the diffusion equation with appropriate boundary conditions, we could determine the oxygen chemical diffusion coefficient and the activation energy. The oxygen diffusion coefficient is 8.9 x 10(-7) cm(2)/s at 900 degrees C and it increases with increase in temperature. Measured activation energy is 0.92 eV, which is slightly lower than that of other oxides in the system SrFe1-xCoxOy.

引用

页码：65 / 71

页数：7

共 26 条

[21] OXYGEN PERMEATION THROUGH PEROVSKITE-TYPE OXIDES
TERAOKA, Y
ZHANG, HM
FURUKAWA, S
YAMAZOE, N
[J]. CHEMISTRY LETTERS, 1985, (11) : 1743 - 1746
[22] EFFECT OF CATION SUBSTITUTION ON THE OXYGEN SEMIPERMEABILITY OF PEROVSKITE-TYPE OXIDES
TERAOKA, Y
NOBUNAGA, T
YAMAZOE, N
[J]. CHEMISTRY LETTERS, 1988, (03) : 503 - 506
[23] DIFFUSION OF POINT DEFECTS IN STRONTIUM TITANATE
WALTERS, LC
GRACE, RE
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1967, 28 (02) : 245 - &
[24] WERNICKE R, 1976, PHILIPS RES REP, V31, P526
[25] PRECISE DETERMINATION OF THE CHEMICAL DIFFUSION-COEFFICIENT OF CALCIUM-DOPED LANTHANUM CHROMITES BY MEANS OF ELECTRICAL-CONDUCTIVITY RELAXATION
YASUDA, I
HIKITA, T
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (05) : 1268 - 1273
[26] YU CJ, 1987, J AM CERAM SOC, V70, pC189

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