Oligomeric tetrathiafulvalenes: A new route toward conjugated TTF dimers and trimers

被引:17
作者
Gautier, N [1 ]
Samuel, R [1 ]
Sahin, Y [1 ]
Levillain, E [1 ]
Leroy-Lhez, S [1 ]
Hudhomme, P [1 ]
机构
[1] CNRS, UMR 6200, F-49045 Angers, France
关键词
D O I
10.1021/ol049620l
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of bis-TTF 1 and tris-TTF 2, linked by an ethenyl spacer, is described using new useful Wittig-type reagents with the introduction of phosphonate functionality on 1,3-dithiole and TTF frameworks. Electrochemical and spectroscopic studies show intramolecular electronic interactions between conjugated TTF units.
引用
收藏
页码:1569 / 1572
页数:4
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