Oligomeric tetrathiafulvalenes: A new route toward conjugated TTF dimers and trimers

被引：17

作者：

Gautier, N ^{[1
]}

Samuel, R ^{[1
]}

Sahin, Y ^{[1
]}

Levillain, E ^{[1
]}

Leroy-Lhez, S ^{[1
]}

Hudhomme, P ^{[1
]}

机构：

[1] CNRS, UMR 6200, F-49045 Angers, France

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 10期

关键词：

D O I：

10.1021/ol049620l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of bis-TTF 1 and tris-TTF 2, linked by an ethenyl spacer, is described using new useful Wittig-type reagents with the introduction of phosphonate functionality on 1,3-dithiole and TTF frameworks. Electrochemical and spectroscopic studies show intramolecular electronic interactions between conjugated TTF units.

引用

收藏

页码：1569 / 1572

页数：4

相关论文

共 28 条

[11]

Giffard H, 2001, J AM CHEM SOC, V123, P3852

[12] Spectroelectrochemistry of electrogenerated tetrathiafulvalene-derivatized poly(thiophenes):: Toward a rational design of organic conductors with mixed conduction [J].

Huchet, L ;

Akoudad, S ;

Levillain, E ;

Roncali, J ;

Emge, A ;

Bäuerle, P .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (40) :7776-7781

[13] New versatile building blocks in tetrathiafulvalene (TTF) chemistry:: 2,3-bis(bromomethyl) and tetrakis(bromomethyl)TTFs [J].

Hudhomme, P ;

Liu, SG ;

Kreher, D ;

Cariou, M ;

Gorgues, A .

TETRAHEDRON LETTERS, 1999, 40 (15) :2927-2930

[14] Helical tetrathiafulvalene oligomers. Synthesis and properties of bi-, ter-, and quatertetrathiafulvalenes [J].

Iyoda, M ;

Hara, K ;

Kuwatani, Y ;

Nagase, S .

ORGANIC LETTERS, 2000, 2 (15) :2217-2220

[15] 1,1-bis(tetrathiafulvalenyl)ethylene. A unique cross-conjugated dimeric tetrathiafulvalene [J].

Iyoda, M ;

Sasaki, S ;

Miura, M ;

Fukuda, M ;

Yamauchi, J .

TETRAHEDRON LETTERS, 1999, 40 (14) :2807-2810

[16]

KHODORKOVSKY V, 1994, ORGANIC CONDUCTORS F, P75

[17] Rigidified tetrathiafulvalene-[60]fullerene assemblies: towards the control of through-space orientation between both electroactive units [J].

Kreher, D ;

Cariou, M ;

Liu, SG ;

Levillain, E ;

Veciana, J ;

Rovira, C ;

Gorgues, A ;

Hudhomme, P .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :2137-2159

[18]

KRIEF A, 1986, TETRAHEDRON, V42, P1209

[19] PREPARATION OF TETRA-THIAFULVALENES (TTF) AND THEIR SELENIUM ANALOGS-TETRASELENAFULVALENES (TSEF) [J].

NARITA, M ;

PITTMAN, CU .

SYNTHESIS-STUTTGART, 1976, (08) :489-514

[20] SYNTHESES AND PROPERTIES OF NOVEL DIMERIC TETRATHIAFULVALENES LINKED WITH AN ETHENYLENE OR ETHYNYLENE SPACER [J].

OTSUBO, T ;

KOCHI, Y ;

BITOH, A ;

OGURA, F .

CHEMISTRY LETTERS, 1994, (11) :2047-2050