Helical tetrathiafulvalene oligomers. Synthesis and properties of bi-, ter-, and quatertetrathiafulvalenes

被引：32

作者：

Iyoda, M ^{[1
]}

Hara, K ^{[1
]}

Kuwatani, Y ^{[1
]}

Nagase, S ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920897, Japan

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 15期

关键词：

D O I：

10.1021/ol0000915

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A series of fully methylthiolated bi-, ter-, and quatertetrathiafulvalenes have been synthesized using cross- and homocoupling reactions of tetrathiafulvalenylzinc derivatives; the tetracation-tetraradical derived from the helical tetrathiafulvalene tetramer exhibits an intramolecular association of the terminal cation-radicals.

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页码：2217 / 2220

页数：4

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