Helical tetrathiafulvalene oligomers. Synthesis and properties of bi-, ter-, and quatertetrathiafulvalenes

被引:32
作者
Iyoda, M [1 ]
Hara, K [1 ]
Kuwatani, Y [1 ]
Nagase, S [1 ]
机构
[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920897, Japan
关键词
D O I
10.1021/ol0000915
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] A series of fully methylthiolated bi-, ter-, and quatertetrathiafulvalenes have been synthesized using cross- and homocoupling reactions of tetrathiafulvalenylzinc derivatives; the tetracation-tetraradical derived from the helical tetrathiafulvalene tetramer exhibits an intramolecular association of the terminal cation-radicals.
引用
收藏
页码:2217 / 2220
页数:4
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