1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal-organic frameworks

被引：165

作者：

Braun, ME ^{[1
]}

Steffek, CD ^{[1
]}

Kim, J ^{[1
]}

Rasmussen, PG ^{[1
]}

Yaghi, OM ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b108031h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The square grid structure of MOF-2, constructed from paddle-wheel units of Zn(II) and 1,4-benzenedicarboxylate (BDC) links, persists for 2-amino-1,4-benzenedicarboxylate (ABDC) links but not for the sterically demanding 2,3,5,6-tetramethyl-1,4-benzenedicarboxylate (TBDC); the dihedral angle between planes of the benzene and carboxylate groups play a determining role in the formation of the paddle-wheel motif.

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收藏

页码：2532 / 2533

页数：2

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