The Inherent Single-Molecule Magnet Character of Trivalent Uranium

被引：94

作者：

Moro, Fabrizio ^{[1
]}

Mills, David P. ^{[1
]}

Liddle, Stephen T. ^{[1
]}

van Slageren, Joris ^{[2
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Stuttgart, Inst Phys Chem, D-70569 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 12期

基金：

欧洲研究理事会; 英国工程与自然科学研究理事会;

关键词：

magnetic properties; single-molecule magnets; slow relaxation; uranium; RELAXATION; COMPLEXES; CHEMISTRY; DYSPROSIUM(III); HYSTERESIS; ANISOTROPY; BEHAVIOR;

D O I：

10.1002/anie.201208015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Uranium magnets: Three uranium(III) complexes with distinctly different structures and compositions are all shown to display slow relaxation of the magnetization. This study greatly expands the range of slowly relaxing uranium complexes, and demonstrates that this behavior is not limited to specific ligand types or molecular symmetries (see picture). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3430 / 3433

页数：4

共 29 条

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