Alcohol to water catalyzed by Pt nanoparticles: an experimental and computational approach

被引：9

作者：

Dehouche, F. ^{[1
]}

Archirel, P. ^{[1
]}

Remita, H. ^{[1
]}

Brodie-Linder, N. ^{[2
,3
]}

Traverse, A. ^{[1
]}

机构：

[1] Univ Paris 11, CNRS, UMR 8000, Chim Phys Lab, F-91405 Orsay, France

[2] CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France

[3] Univ Cergy Pontoise, SOSCO, Dept Chim, F-95031 Cergy Pontoise, France

来源：

RSC ADVANCES | 2012年 / 2卷 / 16期

关键词：

VISIBLE ABSORPTION-SPECTRA; INFRARED-SPECTROSCOPY; CARBONACEOUS DEPOSITS; ORGANIC-MOLECULES; PLATINUM; ETHANOL; OXIDATION; HYDROGENATION; ELECTROOXIDATION; SELECTIVITY;

D O I：

10.1039/c2ra20533e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports alcohol decomposition on Pt nanoparticles. The catalytic degradation of 2-propanol into ethanol, methanol and finally water: 2-propanol -> ethanol -> methanol -> water is observed during the photoreduction process of Pt-II leading to Pt nanoparticles. Formation of the intermediate products has been followed by UV-visible and IR spectroscopy. Quantum chemical results on the Pt-13 particle show that alcohol degradation is possible, and that the mechanism involves the deposition of H, C and CH fragments on the particle's surface.

引用

页码：6686 / 6694

页数：9

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