Application of heterogeneous colloid catalysts for the preparation of fine chemicals

被引：62

作者：

Bonnemann, H ^{[1
]}

Brijoux, W ^{[1
]}

Tilling, AS ^{[1
]}

Siepen, K ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45466 Mulheim, Germany

来源：

TOPICS IN CATALYSIS | 1997年 / 4卷 / 3-4期

关键词：

metal-colloid catalysts; selective cis-hydrogenation; leaf alcohol; glucose-oxidation;

D O I：

10.1023/A:1019152625358

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Preprepared nanometals stabilized by surfactants may be used as precursors for a new type of heterogeneous catalyst. Independent of the support these mono-or plurimetallic precursors may be optimized dependent on the size, composition, and structure of the particles. Further, the active metal surface may be shielded against poisons by the protective shed.-In addition, doping agents may be used in older to enhance the catalytic performance. The cia-selective partial hydrogenation of 3-hexyn-1-ol giving leaf alcohol, a valuable fragrance, and the selective oxidation of glucose giving sodium gluconate are current examples for the application of supported nanometal colloids in fine chemicals catalysis.

引用

页码：217 / 227

页数：11

共 35 条

[1] CATALYTIC-OXIDATION OF GLUCOSE ON BISMUTH-PROMOTED PALLADIUM CATALYSTS
BESSON, M
LAHMER, F
GALLEZOT, P
FUERTES, P
FLECHE, G
[J]. JOURNAL OF CATALYSIS, 1995, 152 (01) : 116 - 121
[2] Nanoscale colloidal metals and alloys stabilized by solvents and surfactants - Preparation and use as catalyst precursors
Bonnemann, H
Braun, G
Brijoux, W
Brinkmann, R
Tilling, AS
Seevogel, K
Siepen, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) : 143 - 162
[3] HIGHLY DISPERSED METAL-CLUSTERS AND COLLOIDS FOR THE PREPARATION OF ACTIVE LIQUID-PHASE HYDROGENATION CATALYSTS
BONNEMANN, H
BRIJOUX, W
BRINKMANN, R
DINJUS, E
FRETZEN, R
JOUSSEN, T
KORALL, B
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1992, 74 (1-3): : 323 - 333
[4] PREPARATION, CHARACTERIZATION, AND APPLICATION OF FINE METAL PARTICLES AND METAL COLLOIDS USING HYDROTRIORGANOBORATES
BONNEMANN, H
BRIJOUX, W
BRINKMANN, R
FRETZEN, R
JOUSSEN, T
KOPPLER, R
KORALL, B
NEITELER, P
RICHTER, J
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1994, 86 (1-3): : 129 - 177
[5] FORMATION OF COLLOIDAL TRANSITION-METALS IN ORGANIC PHASES AND THEIR APPLICATION IN CATALYSIS
BONNEMANN, H
BRIJOUX, W
BRINKMANN, R
DINJUS, E
JOUSSEN, T
KORALL, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (10): : 1312 - 1314
[6] BONNEMANN H, 1995, Z NATURFORSCH B, V50, P333
[7] PREPARATION AND CATALYTIC PROPERTIES OF NR4+-STABILIZED PALLADIUM COLLOIDS
BONNEMANN, H
BRINKMANN, R
NEITELER, P
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 1994, 8 (04) : 361 - 378
[8] Bonnemann H., 1991, ANGEW CHEM, V103, P1344
[9] BONNEMANN H, 1997, IN PRESS INORGANICA
[10] BONNEMANN H, 1996, ADV CATALYSTS NANOST, P165

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