First 3D Pr(III)-Ni(II)-Na(I) polymer and a 3D Pr(III) open network based on pyridine-2,4,6-tricarboxylic acid

被引：148

作者：

Gao, HL ^{[1
]}

Yi, L ^{[1
]}

Ding, B ^{[1
]}

Wang, HS ^{[1
]}

Cheng, P ^{[1
]}

Liao, DZ ^{[1
]}

Yan, SP ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 02期

关键词：

D O I：

10.1021/ic051707v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The self-assembly of pyridine-2,4,6-tricarboxylic acid (H(3)ptc) with metal salts under hydrothermal conditions gave two novel coordination polymers, {[Pr(mu(5)-ptc)(H2O)(2)]center dot 1.5H(2)O}(n) (1) and {Na2NiPr (mu(4)-ClO4)(mu(2)-HOCH2CH2OH)(mu(4)-ptc)(2)(H2O)(8)}center dot 4.5H(2)O}(n) (2). 1 is a 3D open network with five ptc ligands coordinating with one metal center and carboxylate groups linking metal centers to form a (4,13) net. 2 is the first Pr/Ni/Na heterotrimetallic complex, a unique 3D framework containing four different bridged ligands in the system.

引用

页码：481 / 483

页数：3

共 23 条

[1]

Bourne SA, 2001, ANGEW CHEM INT EDIT, V40, P2111, DOI 10.1002/1521-3773(20010601)40:11<2111::AID-ANIE2111>3.0.CO

[2]

2-F

[3] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[4] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[5] SELF-ASSEMBLY OF 10 MOLECULES INTO NANOMETER-SIZED ORGANIC HOST FRAMEWORKS [J].

FUJITA, M ;

OGURO, D ;

MIYAZAWA, M ;

OKA, H ;

YAMAGUCHI, K ;

OGURA, K .

NATURE, 1995, 378 (6556) :469-471

[6] Syntheses and structures of ID and 2D coordination polymers derived from pyridine-2,4,6-tricarboxylic acid [J].

Gao, HL ;

Ding, B ;

Yi, L ;

Cheng, P ;

Liao, DZ ;

Yan, SP ;

Jiang, ZH .

INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (02) :151-154

[7]

GHOAH SK, 2004, INORG CHEM, V43, P5495

[8] New insight into the nature of Cu(TCNQ): Solution routes to two distinct polymorphs and their relationship to crystalline films that display bistable switching behavior [J].

Heintz, RA ;

Zhao, HH ;

Xiang, OY ;

Grandinetti, G ;

Cowen, J ;

Dunbar, KR .

INORGANIC CHEMISTRY, 1999, 38 (01) :144-156

[9]

Kil S.M., 2000, J AM CHEM SOC, V122, P6834

[10] Porous coordination-polymer crystals with gated channels specific for supercritical gases [J].

Kitaura, R ;

Seki, K ;

Akiyama, G ;

Kitagawa, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (04) :428-431

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