Syntheses and structures of ID and 2D coordination polymers derived from pyridine-2,4,6-tricarboxylic acid

被引：47

作者：

Gao, HL ^{[1
]}

Ding, B ^{[1
]}

Yi, L ^{[1
]}

Cheng, P ^{[1
]}

Liao, DZ ^{[1
]}

Yan, SP ^{[1
]}

Jiang, ZH ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 02期

基金：

中国国家自然科学基金;

关键词：

pyridine-2,4,6-tricarboxylic acid; crystal structures; coordination polymers;

D O I：

10.1016/j.inoche.2004.11.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of pyridine-2,4,6-tricarboxylic acid (ptcH(3)) and FeSO4 . 7H(2)O, COCl2 . 6H(2)O or CU(ClO4)(2) . 6H(2)O gave rise to three novel coordination polymers {[M(H2O)(6)][M(ptc)(H2O)(2)](2) . 2H(2)O}(n) (M - Fe(II) (1), Co(II) (2)) and {[CU3(Ptc)(2)(H2O)(8)] . 4-H2O}(n) (3). 1 and 2 are one-dimensional (ID) polymers while 3 exhibits two-dimensional (2D) coordination network, which are due to the different bonding modes of ptcH(3) with metal(II) ions in 1-3. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：151 / 154

页数：4

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