Electrogeneration Of H2O2 In Acid Medium Using Catalysts Modified With Manganese II Phthalocyanine Supported In Printex 6L Carbon

被引：8

作者：

Reis, R. M. ^{[1
]}

Rocha, R. S. ^{[1
]}

Lanza, M. R. V. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Paulo, Brazil

来源：

18 SIMPOSIO BRASILEIRO DE ELETROQUIMICA E ELETROANALITICA (XVIII SIBEE) | 2012年 / 43卷 / 01期

关键词：

OXYGEN REDUCTION REACTION; ELECTRODES; MECHANISM; SURFACE; OXIDE;

D O I：

10.1149/1.4704946

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemical production of hydrogen peroxide by the oxygen reduction reaction (ORR) is becoming a viable alternative as generation takes place in situ, eliminating any problems of transport and storage. In this paper, we have studied the basis of manganese II phthalocyanine (Ph-Mn) catalysts supported in Printex 6L carbon, in order to increase the generation efficiency of H2O2. The results showed that with the catalyst containing 1.0% of Ph-Mn there was an increase in H2O2 production efficiency of 82% in comparison to 80% obtained for unmodified Printex 6L. However, it was observed that the greater the amount of Ph-Mn incorporated into the catalyst, the lower the tendency for the reaction formation of H2O2.

引用

页码：103 / 109

页数：7