Metal vinylidenes and allenylidenes in catalysis: Applications in anti-Markovnikov additions to terminal alkynes and alkene metathesis

被引：453

作者：

Bruneau, C ^{[1
]}

Dixneuf, PH ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Chim, CNRS, UMR 6509, F-35042 Rennes, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 14期

基金：

加拿大自然科学与工程研究理事会;

关键词：

alkene metathesis; allenylidenes; anti-Markovnikov addition; homogeneous catalysis; vinylidenes;

D O I：

10.1002/anie.200501391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The involvement of a catalytic metal vinylidene species was proposed for the first time in 1986 to explain the regioselective formation of vinyl carbamates directly from terminal alkynes, carbon dioxide, and amines. Since this initial report, various metal vinylidenes and allenylidenes, which are key activation intermediates, have proved extremely useful for many alkyne transformations. They have contributed to the rational design of new catalytic reactions. This 20th anniversary is a suitable occasion to present the advancement of organometallic vinylidenes and allenylidenes in catalysis. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2176 / 2203

页数：28

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