Synthesis and structure of a ferrocenylboron dication

被引:28
作者
Braunschweig, Holger [1 ]
Kaupp, Martin [1 ]
Lambert, Christoph [2 ]
Nowak, Doerte [2 ]
Radacki, Krzysztof [1 ]
Schinzel, Sandra [1 ]
Uttinger, Katharina [1 ]
机构
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
[2] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
关键词
D O I
10.1021/ic800876p
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Treatment of the borane Br(2)BFc (Fc = ferrocenyl) with the Lewis base 4-methylpyridine and Na[BAr4f] [Ar-f = 3,5-(CF3)(2)C6H3] afforded the boron dication [FcB(NC5H4-4-Me)(3)][BAr4f](2). This compound is a rare example of a structurally characterized boron dication.
引用
收藏
页码:7456 / 7458
页数:3
相关论文
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