Regioselective iodination of arenes using iodine/NaBO3 • 4H2O system in ionic liquid

被引：14

作者：

Bhilare, Sachin V. ^{[2
]}

Deorukhkar, Amol R. ^{[1
]}

Darvatkar, Nitin B. ^{[2
]}

Salunkhe, Manikrao M. ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India

[2] Inst Sci, Dept Chem, Bombay 400032, Maharashtra, India

来源：

SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 17期

关键词：

catalysis; iodination; ionic liquid; sodium perborate;

D O I：

10.1080/00397910801979395

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild, efficient, and simple protocol was developed for iodination of arenes and heterocyclic compounds with molecular iodine catalyzed by sodium perborate in ionic liquid. The methodology offered iodoarenes in good to excellent yields at room temperature. The protocol proved to be highly selective, as a single isomer was formed exclusively in most of the substrates.

引用

页码：2881 / 2888

页数：8

共 24 条

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