Polymeric δ-MgCl2 nanoribbons

被引：41

作者：

Vittadello, Michele

Stallworth, Philip E.

Alamgir, Faisal M.

Suarez, Sophia

Abbrent, Sabina

Drain, Charles M.

Di Noto, Vito ^{[1
]}

Greenbaum, Steve G.

机构：

[1] Univ Padua, Dept Chem Sci, I-35135 Padua, Italy

[2] Rutgers State Univ, Dept Mat Sci & Engn, Piscataway, NJ 08854 USA

[3] CUNY City Coll, Div Sci, New York, NY 10031 USA

[4] CUNY Hunter Coll, Dept Phys, New York, NY 10021 USA

[5] CUNY Hunter Coll, Dept Chem, New York, NY 10021 USA

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 08期

关键词：

MgCl2; X-ray diffraction; X-ray absorption spectroscopy; solid state NMR;

D O I：

10.1016/j.ica.2006.01.044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

delta-MgCl2 has relevant applications in the field of electrochemical energy storage and Ziegler-Natta catalysis. Here, we clarify the short-range structural peculiarities that make the disordered phase delta-MgCl2 extremely chemically active relative to the higher lattice energy phases, alpha-MgCl2 and beta-MgCl2, X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS) and nuclear magnetic resonance (NMR) results are included. These findings, demonstrate the existence Of [MgCl2](n) nanoribbons and active nanosurfaces in delta-MgCl2 and provide new insight about the nature of the bonding in the allotropic forms Of MgCl2. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2513 / 2518

页数：6

共 24 条

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