Synthesis of P,S,O-ligands incorporating a planar chiral ferrocenyl motif

被引：36

作者：

Spencer, J

Gramlich, V

Hausel, R

Togni, A

机构：

[1] ETH ZENTRUM,INORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

[2] ETH ZENTRUM,INST CRYSTALLOG & PETROG,CH-8092 ZURICH,SWITZERLAND

[3] CIBA GEIGY LTD,CENT RES SERV,FD 6,CH-8092 ZURICH,SWITZERLAND

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 01期

关键词：

D O I：

10.1016/0957-4166(95)00416-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The sodium salt of (R)-1-[(S)-(diphenylphosphino)ferrocenyl]ethyl mercaptan 1 reacted with racemic epoxide 2 to furnish the P,S,O system 3 as a separable mixture of diastereoisomers. The absolute configuration of (R, S, S)-(S)-4a and that of the palladium pi-allyl complex 6a were established by crystal structure determinations.

引用

收藏

页码：41 / 44

页数：4

相关论文

共 19 条

[1] A NEW STEROSELECTIVE APPROACH TO CHIRAL FERROCENYL LIGANDS FOR ASYMMETRIC CATALYSIS [J].

ABBENHUIS, HCL ;

BURCKHARDT, U ;

GRAMLICH, V ;

TOGNI, A ;

ALBINATI, A ;

MULLER, B .

ORGANOMETALLICS, 1994, 13 (11) :4481-4493

[2] SUCCESSFUL APPLICATION OF A FORGOTTEN PHOSPHINE IN ASYMMETRIC CATALYSIS - A 9-PHOSPHABICYCLO[3.3.1]NON-9-YL FERROCENE DERIVATIVE AS CHIRAL LIGAND [J].

ABBENHUIS, HCL ;

BURCKHARDT, U ;

GRAMLICH, V ;

KOLLNER, C ;

PREGOSIN, PS ;

SALZMANN, R ;

TOGNI, A .

ORGANOMETALLICS, 1995, 14 (02) :759-766

[3]

ABBENHUIS HCL, IN PRESS

[4] PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC SUBSTITUTION - A LIGAND DESIGN INCORPORATING STERIC AND ELECTRONIC EFFECTS [J].

ALLEN, JV ;

COOTE, SJ ;

DAWSON, GJ ;

FROST, CG ;

MARTIN, CJ ;

WILLIAMS, JMJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (15) :2065-2072

[5] ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION - ELECTRONIC AND STERIC EFFECTS OF THE LIGAND [J].

ALLEN, JV ;

BOWER, JF ;

WILLIAMS, JMJ .

TETRAHEDRON-ASYMMETRY, 1994, 5 (10) :1895-1898

[6]

BURCKHARDT U, IN PRESS ORGANOMETAL

[7] SELECTIVITY IN PALLADIUM CATALYZED ALLYLIC SUBSTITUTION [J].

FROST, CG ;

HOWARTH, J ;

WILLIAMS, JMJ .

TETRAHEDRON-ASYMMETRY, 1992, 3 (09) :1089-1122

[8] OPTICALLY-ACTIVE RUTHENOCENYLBIS(PHOSPHINES) - NEW EFFICIENT CHIRAL PHOSPHINE-LIGANDS FOR CATALYTIC ASYMMETRIC REACTIONS [J].

HAYASHI, T ;

OHNO, A ;

LU, SJ ;

MATSUMOTO, Y ;

FUKUYO, E ;

YANAGI, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) :4221-4226

[9]

HAYASHI T, 1995, FERROCENES, P105

[10] SYNTHESIS AND ABSOLUTE STEREOCHEMISTRY OF CIS-1,2-INDANDIOLS AND TRANS-1,2-INDANDIOLS - METABOLITES OF INDENE AND 2-INDANONE [J].

IMUTA, M ;

ZIFFER, H .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (23) :4540-4542