ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION - ELECTRONIC AND STERIC EFFECTS OF THE LIGAND

被引：123

作者：

ALLEN, JV ^{[1
]}

BOWER, JF ^{[1
]}

WILLIAMS, JMJ ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(00)86260-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ligands containing an enantiomerically pure oxazoline and a sulfur-containing tether have been examined for their ability to provide asymmetric induction in palladium catalysed allylic substitution reaction. The enantioselectivity obtained was found to be highly dependent upon the stereochemistry at sulfur (for sulfoxides), and also somewhat dependent upon the nature of the aryl group attached to the sulfur.

引用

页码：1895 / 1898

页数：4

共 20 条

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