Chemoselective allylation of aldimine with allyltriethylgermane by the combined use of BF3•OEt2 and AcOH

被引：46

作者：

Akiyama, T ^{[1
]}

Iwai, J ^{[1
]}

Onuma, Y ^{[1
]}

Kagoshima, H ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 171, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 21期

关键词：

D O I：

10.1039/a907538k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allyltriethylgermane reacts with aldimines in preference to aldehydes by means of BF3. OEt2 and AcOH to afford homoallylic amines in high yields; three component syntheses of homoallytic amines starting from aldehyde, aniline and allylgermane were successfully achieved.

引用

页码：2191 / 2192

页数：2

共 20 条

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