Temperature-triggered gate opening for gas adsorption in microporous manganese formate

被引：70

作者：

Kim, Hyunuk ^{[2
,3
]}

Samsonenko, Denis G. ^{[2
,3
]}

Yoon, Minyoung ^{[2
,3
]}

Yoon, Ji Woong ^{[1
]}

Hwang, Young Kyu ^{[1
]}

Chang, Jong-San ^{[1
]}

Kim, Kimoon ^{[2
,3
]}

机构：

[1] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, Taejon 305600, South Korea

[2] Pohang Univ Sci & Technol, Natl Creat Res Initiat Ctr Smart Supramol, Pohang 790784, South Korea

[3] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 39期

关键词：

D O I：

10.1039/b811087e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature.

引用

收藏

页码：4697 / 4699

页数：3

相关论文

共 52 条

[1] A crystalline organic substrate absorbs methane under STP conditions [J].

Atwood, JL ;

Barbour, LJ ;

Thallapally, PK ;

Wirsig, TB .

CHEMICAL COMMUNICATIONS, 2005, (01) :51-53

[2] CRYSTALLINE ZEOLITES .1. THE PROPERTIES OF A NEW SYNTHETIC ZEOLITE, TYPE-A [J].

BRECK, DW ;

EVERSOLE, WG ;

MILTON, RM ;

REED, TB ;

THOMAS, TL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (23) :5963-5971

[3]

BRECK DW, 1974, ZEOLITE MOL SIEVES, P636

[4] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules [J].

Chen, Banglin ;

Ma, Shengqian ;

Zapata, Fatima ;

Fronczek, Frank R. ;

Lobkovsky, Emil B. ;

Zhou, Hong-Cai .

INORGANIC CHEMISTRY, 2007, 46 (04) :1233-1236

[5] High H2 adsorption in a microporous metal-organic framework with open metal sites [J].

Chen, BL ;

Ockwig, NW ;

Millward, AR ;

Contreras, DS ;

Yaghi, OM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749

[6] Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].

Chun, H ;

Dybtsev, DN ;

Kim, H ;

Kim, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529

[7] Design of new materials for methane storage [J].

Düren, T ;

Sarkisov, L ;

Yaghi, OM ;

Snurr, RQ .

LANGMUIR, 2004, 20 (07) :2683-2689

[8]

Dybstev D.N., 2004, Angew. Chem. Int Ed, V43, P5033

[9] A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity [J].

Dybtsev, DN ;

Nuzhdin, AL ;

Chun, H ;

Bryliakov, KP ;

Talsi, EP ;

Fedin, VP ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :916-920

[10] Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties [J].

Dybtsev, DN ;

Chun, H ;

Yoon, SH ;

Kim, D ;

Kim, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :32-33

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