Characterization and electrochromic properties of CuxNi1-xO films prepared by sol-gel dip-coating

被引:38
作者
He, ZP [1 ]
Ji, ZG [1 ]
Zhao, SC [1 ]
Wang, C [1 ]
Liu, K [1 ]
Ye, ZZ [1 ]
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
关键词
CuxNi1-O-x films; electrochromic; sol-gel; dip-coating;
D O I
10.1016/j.solener.2005.02.007
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
CuxNi1-xO electrochromic thin films were prepared by sol-gel dip coating and characterized by XRD, UV-vis absorption and electrochromic test. XRD results show that the structure of the Cu-x Ni1-xO thin films is still in cubic NiO structure. UV-vis absorption spectra show that the absorption edges of the CuxNi1-xO films can be tuned front 335 nm (x = 0) to 550 nm (x = 0.3). and the transmittance of the colored films decrease as the content of Cu increases. CuxNi1-xO films show good electrochromic behavior, both the coloring and bleaching time for a Cu0.2Ni0.8O film were less than 1 s, with a variation of transmittance up to 75%, at the wavelength of 632.8 nm. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:226 / 230
页数:5
相关论文
共 20 条
[1]   Synthesis and electrochromic behavior of lithium-doped WO3 films [J].
Avellaneda, CO ;
Bueno, PR ;
Bulhoes, LOS .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 290 (2-3) :115-121
[2]   Electrochromism in nickel oxide films containing Mg, Al, SiV, Zr, Nb, Ag, or Ta [J].
Avendaño, E ;
Azens, A ;
Niklasson, GA ;
Granqvist, CG .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 84 (1-4) :337-350
[3]   Theoretical and experimental results on Au-NiO and Au-CoO electrochromic composite films [J].
Fantini, MCA ;
Ferreira, FF ;
Gorenstein, A .
SOLID STATE IONICS, 2002, 152 :867-872
[4]   Electrochromic nickel oxide thin films deposited under different sputtering conditions [J].
Ferreira, FF ;
Tabacniks, MH ;
Fantini, MCA ;
Faria, IC ;
Gorenstein, A .
SOLID STATE IONICS, 1996, 86-8 :971-976
[5]   Composite Au-NiO films [J].
Ferreira, FF ;
Haddad, PS ;
Fantini, MCA ;
Brito, GES .
SOLID STATE IONICS, 2003, 165 (1-4) :161-168
[6]   Theoretical optical properties of composite metal-NiO films [J].
Ferreira, FF ;
Fantini, MCA .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (19) :2386-2392
[7]   Giant magnetoresistance effect of spin valve Co/Pd/Co/NiO [J].
Gouda, W ;
Shiiki, K .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 205 (2-3) :136-142
[8]   The response of a NiOx thin film to a step potential and its electrochromic mechanism [J].
Jiang, SR ;
Yan, PX ;
Feng, BX ;
Cai, XM ;
Wang, J .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 77 (02) :384-389
[9]   Studies on electrochromic properties of nickel oxide thin films prepared by spray pyrolysis technique [J].
Kadam, LD ;
Patil, PS .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 69 (04) :361-369
[10]   The role of thermal analysis in optimization of the electrochromic effect of nickel oxide thin films, prepared by the sol-gel method: Part II [J].
Korosec, RC ;
Bukovec, P .
THERMOCHIMICA ACTA, 2004, 410 (1-2) :65-71