One-dimensional Ag(I) organometallic coordination polymers generated from a fulvene-based ligand

被引：1

作者：

Wang, P

Ma, JP

Huang, RQ

Dong, YB ^{[1
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China

[2] Shandong Normal Univ, Shandong Key Lab Chem Funct Mat, Jinan 250014, Peoples R China

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2006年 / 59卷 / 03期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1071/CH05297

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new fulvene-based ligand L was synthesized and its coordination chemistry with Ag(I) ion has been investigated. Two novel Ag(I) polymeric complexes, [Ag2L2 center dot 5.5(C6H6)]SbF6 (1) and [AgL center dot 2.5(C6H6)]SbF6 (2), were obtained by combination of L with AgSbF6 in one-pot reaction. X-Ray single-crystal analysis revealed that both 1 and 2 crystallize in triclinic system P (1) over bar. In 1 and 2, the ligand L adopts a trans-conformation to bind the Ag(I) centres into a one-dimensional twin-chain structure through either Ag-O coordination or pi-pi interactions.

引用

页码：207 / 210

页数：4

共 25 条

[21] Supramolecular engineering of chiral and acentric 2D networks. Synthesis, structures, and second-order nonlinear optical properties of bis(nicotinato)zinc and bis{3-[2-(4-pyridyl)ethenyl]benzoato}cadmium [J].