Polar acetalization and transacetalization in the gas phase: The Eberlin reaction

被引：73

作者：

Cooks, RG ^{[1
]}

Chen, H

Eberlin, MN

Zheng, X

Tao, WA

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

[2] Purdue Univ, Dept Biochem, W Lafayette, IN 47907 USA

[3] Univ Estadual Campinas, Inst Chem, Thomson Mass Spectrometry Lab, BR-13083 Campinas, SP, Brazil

[4] Gilead Sci Co, Foster City, CA 94404 USA

来源：

CHEMICAL REVIEWS | 2006年 / 106卷 / 01期

关键词：

D O I：

10.1021/cr0400921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview of the large body of work published on the Eberlin acetalization and transacetalization reactions and related gas phase ion/molecule reactions is given. The reaction occurs for many classes of amphoteric cations with dual Lewis acidity and basicity with cyclic acetals, diols, and related compounds. Extensive fundamental, synthetic, and analytical applications of the gas-phase Eberlin reaction, as well as close connections with condensed-phase chemistry are reviewed.

引用

页码：188 / 211

页数：24

共 265 条

[71] Unified mechanistic concept of electrophilic aromatic nitration: Convergence of computational results and experimental data [J].