Better understanding of mechanochemical reactions: Raman monitoring reveals surprisingly simple 'pseudo-fluid' model for a ball milling reaction

被引：108

作者：

Ma, Xiaohe ^{[1
]}

Yuan, Wenbing ^{[2
]}

Bell, Steven E. J. ^{[1
]}

James, Stuart L. ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

[2] Hainan Univ, Key Lab Trop Biol Resources, Minist Educ, Haikou 570228, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 13期

关键词：

FRAMEWORKS;

D O I：

10.1039/c3cc47898j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quantitative monitoring of a mechanochemical reaction by Raman spectroscopy leads to a surprisingly straightforward second-order kinetic model in which the rate is determined simply by the frequency of reactive collisions between reactant particles.

引用

页码：1585 / 1587

页数：3

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