High-Performance Liquid and Solid Dye-Sensitized Solar Cells Based on a Novel Metal-Free Organic Sensitizer

被引:140
作者
Wang, Mingkui [2 ]
Xu, Mingfei [1 ]
Shi, Dong [1 ]
Li, Renzhi [1 ]
Gao, Feifei [1 ]
Zhang, Guangliang [1 ]
Yi, Zhihui [1 ]
Humphry-Baker, Robin [2 ]
Wang, Peng [1 ]
Zakeeruddin, Shaik M. [2 ]
Graetzel, Michael [2 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymers & Chem, Changchun 130022, Peoples R China
[2] Swiss Fed Inst Technol, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
基金
美国国家科学基金会; 瑞士国家科学基金会;
关键词
D O I
10.1002/adma.200801178
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new metal-free organic sensitizer (see figure) for high-performance and applicable dye-sensitized solar cells is presented. In combination with a solvent-free ionic liquid electrolyte, a similar to 7% cell made with this sensitizer shows all excellent stability measured under thermal and light-soaking dual stress. For the first time a 4.8% efficiency is reached for all-solid-state dye-sensitized solar cells based oil all organic dye.
引用
收藏
页码:4460 / 4463
页数:4
相关论文
共 27 条
[11]   HIGHLY EFFICIENT SEMICONDUCTING TIO2 PHOTOELECTRODES PREPARED BY AEROSOL PYROLYSIS [J].
KAVAN, L ;
GRATZEL, M .
ELECTROCHIMICA ACTA, 1995, 40 (05) :643-652
[12]  
KIM S, 2006, J AM CHEM SOC, V128, P16071
[13]   Effect of an adsorbent on recombination and band-edge movement in dye-sensitized TiO2 solar cells:: Evidence for surface passivation [J].
Kopidakis, Nikos ;
Neale, Nathan R. ;
Frank, Arthur J. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (25) :12485-12489
[14]   Alkyl-functionalized organic dyes for efficient molecular photovoltaics [J].
Koumura, Nagatoshi ;
Wang, Zhong-Sheng ;
Mori, Shogo ;
Miyashita, Masanori ;
Suzuki, Eiji ;
Hara, Kohjiro .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (44) :14256-14257
[15]   Charge transport and recombination in a nanoscale interpenetrating network of n-type and p-type semiconductors:: Transient photocurrent and photovoltage studies of TiO2/Dye/CuSCN photovoltaic cells [J].
O'Regan, BC ;
Lenzmann, F .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (14) :4342-4350
[16]  
Pope M., 1999, ELECT PROCESSES ORGA
[17]   Comparison of dye-sensitized ZnO and TiO2 solar cells:: Studies of charge transport and carrier lifetime [J].
Quintana, Maria ;
Edvinsson, Tomas ;
Hagfeldt, Anders ;
Boschloo, Gerrit .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (02) :1035-1041
[18]   Organic dye for highly efficient solid-state dye-sensitized solar cells [J].
Schmidt-Mende, L ;
Bach, U ;
Humphry-Baker, R ;
Horiuchi, T ;
Miura, H ;
Ito, S ;
Uchida, S ;
Grätzel, M .
ADVANCED MATERIALS, 2005, 17 (07) :813-+
[19]   Organic-based photovoltaics. toward low-cost power generation [J].
Shaheen, SE ;
Ginley, DS ;
Jabbour, GE .
MRS BULLETIN, 2005, 30 (01) :10-19
[20]   Efficiency enhancements in solid-state hybrid solar cells via reduced charge recombination and increased light capture [J].
Snaith, Henry J. ;
Moule, Adam J. ;
Klein, Cedric ;
Meerholz, Klaus ;
Friend, Richard H. ;
Gratzel, Michael .
NANO LETTERS, 2007, 7 (11) :3372-3376