Polyterthiophene appended by transition-metal cluster:: electropolymerization of 3′-[CCo3(CO)9]-5,2′:5′,2"-terthiophene

被引：13

作者：

Kang, BS

Kim, DH

Jung, TS

Jang, EK

Pak, Y

Shin, SC ^{[1
]}

Park, DS

Shim, YB

机构：

[1] Gyeongsang Natl Univ, Res Inst Nat Sci, Dept Chem, Chinju 660701, South Korea

[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Dept Biochem, Chinju 660701, South Korea

[3] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

来源：

SYNTHETIC METALS | 1999年 / 105卷 / 01期

关键词：

electrochemical polymerization; terthiophene; cluster; electrode;

D O I：

10.1016/S0379-6779(99)00057-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Terthiophene, to which cobalt carbonyl cluster complex is pi-conjugated, 3'-[CCo3(CO)(9)]-5,2' :5',2 "-terthiophene (3'-CoTTh), was prepared by reaction of 3'-chloromercuro-5,2' :5',2 "-terthiophene with HCCo3(CO)(9). The molecular structure of 3'-CoTTh is identified by spectroscopic methods and elemental analysis. Cyclic voltammetry of 3'-CoTTh showed deposition of electroactive polymer films on the electrode surface. The absorption spectra of 3'-CoTTh and its polymer films are presented. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：9 / 12

页数：4

相关论文

共 30 条

[1] THE KINETICS OF ELECTRON-TRANSFER IN THE THIONINE-COATED ELECTRODE [J].

ALBERY, WJ ;

BOUTELLE, MG ;

COLBY, PJ ;

HILLMAN, AR .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 133 (01) :135-145

[2] POLY(PYRROLE MANGANESE PORPHYRIN) FILM ELECTRODE AS A CATALYST IN ELECTRO-ASSISTED OXIDATION REACTIONS USING MOLECULAR-OXYGEN - COMPARISON WITH DESCRIBED HOMOGENEOUS SYSTEMS [J].

BEDIOUI, F ;

MOISY, P ;

DEVYNCK, J ;

SALMON, L ;

BIEDCHARRETON, C .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 56 (1-3) :267-275

[3] METALLOPORPHYRIN POLYPYRROLE FILM ELECTRODE - CHARACTERIZATION AND CATALYTIC APPLICATION [J].

BEDIOUI, F ;

BONGARS, C ;

DEVYNCK, J ;

BIEDCHARRETON, C ;

HINNEN, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 207 (1-2) :87-99

[4] PARAMAGNETIC ORGANOMETALLIC MOLECULES .2. ELECTROCHEMICAL INVESTIGATION OF TRICOBALT CARBON CLUSTER [J].

BOND, AM ;

PEAKE, BM ;

ROBINSON, BH ;

SIMPSON, J ;

WATSON, DJ .

INORGANIC CHEMISTRY, 1977, 16 (02) :410-415

[5]

CARPITA A, 1985, GAZZ CHIM ITAL, V115, P575

[6]

Christopher M. A. Brett., 1993, ELECTROCHEMISTRY PRI

[7] HETERONUCLEAR MIXED-VALENCE COMPOUNDS - TRANSITION-METAL CARBONYL CLUSTERS WITH MULTIPLE REDOX CENTERS [J].

COLBRAN, S ;

SIMPSON, J ;

ROBINSON, BH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (23) :1361-1362

[8] ELECTRON-TRANSFER IN ORGANOMETALLIC CLUSTERS .3. ELECTRON-TRANSFER AND MIXED-VALENCE PROPERTIES OF SUBSTITUTED FERROCENE TRICOBALT CARBON CLUSTERS [J].

COLBRAN, SB ;

ROBINSON, BH ;

SIMPSON, J .

ORGANOMETALLICS, 1983, 2 (08) :952-957

[9] TRIRUTHENIUM CLUSTER POLYPYRROLE FILMS - A REMARKABLY STABLE IMMOBILIZED RELAY AT HIGHLY POSITIVE POTENTIALS - ITS APPLICATION TO THE ELECTROCATALYTIC OXIDATION OF BENZYL ALCOHOL [J].

COSNIER, S ;

DERONZIER, A ;

LLOBET, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 280 (01) :213-219

[10] POLY(PYRROLE) AS A SUPPORT FOR ELECTROCATALYTIC MATERIALS [J].

CURRAN, D ;

GRIMSHAW, J ;

PERERA, SD .

CHEMICAL SOCIETY REVIEWS, 1991, 20 (03) :391-404