Polyterthiophene appended by transition-metal cluster:: electropolymerization of 3′-[CCo3(CO)9]-5,2′:5′,2"-terthiophene

被引：13

作者：

Kang, BS

Kim, DH

Jung, TS

Jang, EK

Pak, Y

Shin, SC ^{[1
]}

Park, DS

Shim, YB

机构：

[1] Gyeongsang Natl Univ, Res Inst Nat Sci, Dept Chem, Chinju 660701, South Korea

[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Dept Biochem, Chinju 660701, South Korea

[3] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

来源：

SYNTHETIC METALS | 1999年 / 105卷 / 01期

关键词：

electrochemical polymerization; terthiophene; cluster; electrode;

D O I：

10.1016/S0379-6779(99)00057-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Terthiophene, to which cobalt carbonyl cluster complex is pi-conjugated, 3'-[CCo3(CO)(9)]-5,2' :5',2 "-terthiophene (3'-CoTTh), was prepared by reaction of 3'-chloromercuro-5,2' :5',2 "-terthiophene with HCCo3(CO)(9). The molecular structure of 3'-CoTTh is identified by spectroscopic methods and elemental analysis. Cyclic voltammetry of 3'-CoTTh showed deposition of electroactive polymer films on the electrode surface. The absorption spectra of 3'-CoTTh and its polymer films are presented. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：9 / 12

页数：4

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