Effects of carbonization temperatures on characteristics of porosity in coconut shell chars and activated carbons derived from carbonized coconut shell chars

被引:310
作者
Li, Wei [1 ,2 ]
Yang, Kunbin [1 ]
Peng, Jinhui [1 ]
Zhang, Libo [1 ]
Guo, Shenghui [1 ]
Xia, Hongying [1 ]
机构
[1] Kunming Univ Sci & Technol, Fac Mat & Met Engn, Kunming 650093, Peoples R China
[2] Kunming Univ Sci & Technol, Fac Sci, Kunming 650093, Peoples R China
关键词
activated carbon; carbonization temperature; coconut shells; characteristics of porosity;
D O I
10.1016/j.indcrop.2008.02.012
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
A series of experiments have been conducted to study the effects of different carbonization temperatures (400, 600, 800 and 1000 degrees C) on characteristics of porosity in carbonized coconut shell char and activated carbon derived from carbonized coconut shell char with different activation times (30, 60, 90 and 120 min) at activation temperature of 900 degrees C. The results showed that high temperature carbonized coconut shell char and activated carbon samples derived from high temperature carbonized coconut shell chars had higher BET surface area, total volume, micropore volume and yield as compared to those of low temperature carbonized coconut shell char and activated carbon derived from low temperature carbonized coconut shell char. The BET surface area, total volume and micropore volume of activated carbon prepared from char obtained at 1000 degrees C with activation time of 120 min were 1926 m(2)/g, 1.26 cm(3)/g and 0.931 cm(3)/g, respectively. From the results, it was concluded that we could produce high surface area activated carbons from coconut shells using physical activation (steam activation) by proper selections of carbonization temperature and activation time. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:190 / 198
页数:9
相关论文
共 43 条
[1]   The evolution of the pore structure of coconut shells during the preparation of coconut shell-based activated carbons [J].
Achaw, Osei-Wusu ;
Afrane, George .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 112 (1-3) :284-290
[2]   Microporous activated carbon prepared from coconut shells using chemical activation with zinc chloride [J].
Azevedo, Diana C. S. ;
Araujo, J. Cassia S. ;
Bastos-Neto, Moises ;
Torres, A. Eurico B. ;
Jaguarible, Emerson F. ;
Cavalcante, Celio L. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 100 (1-3) :361-364
[3]   Preparation of activated carbons from coffee residue for the adsorption of formaldehyde [J].
Boonamnuayvitaya, V ;
Sae-ung, S ;
Tanthapanichakoon, W .
SEPARATION AND PURIFICATION TECHNOLOGY, 2005, 42 (02) :159-168
[4]   Preparation and characterization of activated carbon from date stones by physical activation with steam [J].
Bouchelta, Chafia ;
Medjram, Mohamed Salah ;
Bertrand, Odile ;
Bellat, Jean-Pierre .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2008, 82 (01) :70-77
[5]   Chemisorptions of gases on iron synthetic ammonia catalysts [J].
Brunauer, S ;
Emmett, PH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :1732-1746
[6]  
Byrne J.F., 1995, POROSITY CARBONS CHA, P1
[7]  
CIGDEM SS, 2006, MICROPOR MESOPOR MAT, V88, P126
[8]   Non-conventional low-cost adsorbents for dye removal: A review [J].
Crini, G .
BIORESOURCE TECHNOLOGY, 2006, 97 (09) :1061-1085
[9]   Adsorption - from theory to practice [J].
Dabrowski, A .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2001, 93 (1-3) :135-224
[10]   Adsorption of phenolic compounds by activated carbon - a critical review [J].
Dabrowski, A ;
Podkoscielny, P ;
Hubicki, Z ;
Barczak, M .
CHEMOSPHERE, 2005, 58 (08) :1049-1070