Model for the conductivity of ionic liquids based on an infinite dilution of holes

被引：144

作者：

Abbott, AP ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

CHEMPHYSCHEM | 2005年 / 6卷 / 12期

关键词：

conducting materials; ionic liquids; liquid; molten salts; Stokes-Einstein equation;

D O I：

10.1002/cphc.200500283

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Charge transport in an ambient-temperature ionic liquid is limited by the mobility of suitably sized voids into which ions can migrate (see figure). This allows conductivity data to be simply analyzed by using the Stokes-Einstein equation. The mechanism of charge transport is contrasted with that in high-temperature molten salts, which is different from that in low-temperature systems. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2502 / 2505

页数：4

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