Synthesis of new β-substituted meso-tetraphenylporphyrins via 1,3-dipolar cycloaddition reactions.: 1

被引：47

作者：

Silva, AMG ^{[1
]}

Tomé, AC ^{[1
]}

Neves, MGPMS ^{[1
]}

Silva, AMS ^{[1
]}

Cavaleiro, JAS ^{[1
]}

机构：

[1] Univ Aveiro, Dept Chem, P-3810 Aveiro, Portugal

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 03期

关键词：

D O I：

10.1021/jo0106703

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The azomethine ylide generated from the reaction of (beta-formyl-meso-tetraphenylporphyrinato)nickel(II) with N-methylglycine reacts with a range of dipolarophiles, yielding new beta-substituted-meso-tetraphenylporphyrins.. The regio- and stereochemistry of the new compounds was established using one- and two-dimensional NMR techniques.

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页码：726 / 732

页数：7

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