Immobilization and electrochemical properties of anionic complexes on a V2O5/surfactant nanocomposite

被引：7

作者：

da Silva, LF

Profeti, LPR

Stradiotto, NR

Oliveira, HP

机构：

[1] Univ Sao Paulo, Dept Quim, Fac Filosofia Ciencias & Letras Ribeirao Pret, BR-14040901 Ribeirao Preto, SP, Brazil

[2] Univ Estadual Paulista, Inst Quim, BR-14900900 Araraquara, SP, Brazil

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2002年 / 298卷 / 2-3期

基金：

巴西圣保罗研究基金会;

关键词：

D O I：

10.1016/S0022-3093(02)00922-5

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

in this work, we report a new way of modifying an electrode by combining the intrinsic conductivity property of vanadium pentoxide xerogel with its water insolubility in the presence of the cationic surfactant N-cetyl-N,N,N,trimethyl-ammonium bromide (CTA(+)Br(-)). The obtained hybrid compound enables the immobilization of electroactive anions such as hexacyanoferrate (III) ([Fe(CN)(6)](3-)) and its analogue pentacyanonitrosylferrate (II) ([Fe(CN)(5)NO](2-)), rather than cations. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：213 / 218

页数：6

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