Polyamino acids as catalysts in asymmetric synthesis

被引：83

作者：

Porter, MJ ^{[1
]}

Roberts, SM ^{[1
]}

Skidmore, J ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

BIOORGANIC & MEDICINAL CHEMISTRY | 1999年 / 7卷 / 10期

关键词：

amino acids and derivatives; peptides and polypeptides; polymers; reviews;

D O I：

10.1016/S0968-0896(99)00144-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The use of polyamino acids in asymmetric organic synthesis is reviewed. Particular emphasis is placed on the asymmetric epoxidation of alpha,beta-unsaturated ketones with hydrogen peroxide in the presence of polyalanine or polyleucine, and further transformations of the epoxide products. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2145 / 2156

页数：12

共 83 条

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