Effects of confinement on freezing and melting

被引:769
作者
Alba-Simionesco, C.
Coasne, B.
Dosseh, G.
Dudziak, G.
Gubbins, K. E.
Radhakrishnan, R.
Sliwinska-Bartkowiak, M.
机构
[1] Univ Paris 11, CNRS, UMR 8000, Chim Phys Lab, F-91405 Orsay, France
[2] N Carolina State Univ, Ctr High Performance Simulat, Raleigh, NC 27695 USA
[3] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA
[4] Adam Mickiewicz Univ, Inst Phys, PL-61614 Poznan, Poland
[5] Univ Penn, Dept Bioengn, Philadelphia, PA 19104 USA
关键词
D O I
10.1088/0953-8984/18/6/R01
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We present a review of experimental, theoretical, and molecular simulation studies of confinement effects on freezing and melting. We consider both simple and more complex adsorbates that are confined in various environments (slit or cylindrical pores and also disordered porous materials). The most commonly used molecular simulation, theoretical and experimental methods are first presented. We also provide a brief description of the most widely used porous materials. The current state of knowledge on the effects of confinement on structure and freezing temperature, and the appearance of new surface-driven and confinement-driven phases are then discussed. We also address how confinement affects the glass transition.
引用
收藏
页码:R15 / R68
页数:54
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