Solvent-free selective photocatalytic oxidation of benzyl alcohol to benzaldehyde by molecular oxygen using 9-phenyl-10-methylacridinium

被引：83

作者：

Ohkubo, K ^{[1
]}

Suga, K ^{[1
]}

Fukuzumi, S ^{[1
]}

机构：

[1] Osaka Univ, SORST, Japan Sci & Technol Agcy, Grad Sch Engn,Dept Mat & Life Sci, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 19期

关键词：

D O I：

10.1039/b518127e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phenyl-10-methylacridium ion acts as an effective photocatalyst for solvent free selective photocatalytic oxidation of benzyl alcohol to benzaldehyde under visible light irradiation via efficient photoinduced electron transfer from benzyl alcohol to the singlet excited state of the acridinium ion.

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页码：2018 / 2020

页数：3

相关论文

共 28 条

[1] Effect of alkali-metal promoter on silica-supported copper catalysts in benzyl alcohol oxidation [J].

Arai, M ;

Nishiyama, S ;

Tsuruya, S ;

Masai, M .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (14) :2631-2636

[2]

Baciocchi E, 2001, CHEM-EUR J, V7, P1408, DOI 10.1002/1521-3765(20010401)7:7<1408::AID-CHEM1408>3.0.CO

[3]

2-M

[4] Selective oxidation of alcohols in a continuous multifunctional reactor: Ruthenium oxide catalysed oxidation of benzyl alcohol [J].

Bavykin, DV ;

Lapkin, AA ;

Kolaczkowski, ST ;

Plucinski, PK .

APPLIED CATALYSIS A-GENERAL, 2005, 288 (1-2) :175-184

[5] Naflon perfluorinated membranes treated in Fenton media: radical species detected by ESR spectroscopy [J].

Bosnjakovic, A ;

Schlick, S .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (14) :4332-4337

[6]

Choudary BM, 2001, ANGEW CHEM INT EDIT, V40, P763, DOI 10.1002/1521-3773(20010216)40:4<763::AID-ANIE7630>3.0.CO

[7]

2-T

[8] Solvent-free liquid phase oxidation of benzyl alcohol to benzaldehyde by molecular oxygen using non-noble transition metal containing hydrotalcite-like solid catalysts [J].

Choudhary, VR ;

Chaudhari, PA ;

Narkhede, VS .

CATALYSIS COMMUNICATIONS, 2003, 4 (04) :171-175

[9] Efficient catalysis of rare-earth metal ions in photoinduced electron-transfer oxidation of benzyl alcohols by a flavin analogue [J].

Fukuzumi, S ;

Yasui, K ;

Suenobu, T ;

Ohkubo, K ;

Fujitsuka, M ;

Ito, O .

JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (46) :10501-10510

[10] Photoalkylation of 10-alkylacridinium ion via a charge-shift type of photoinduced electron transfer controlled by solvent polarity [J].

Fukuzumi, S ;

Ohkubo, K ;

Suenobu, T ;

Kato, K ;

Fujitsuka, M ;

Ito, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (35) :8459-8467