Metal-organic framework membranes with layered structure prepared within the porous support

被引：30

作者：

Hara, Nobuo ^{[1
]}

Yoshimune, Miki ^{[1
]}

Negishi, Hideyuki ^{[1
]}

Haraya, Kenji ^{[1
]}

Hara, Shigeki ^{[1
]}

Yamaguchi, Takeo ^{[2
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Inst Innovat Sustainable Chem, Tsukuba, Ibaraki 3058565, Japan

[2] Tokyo Inst Technol, Chem Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

RSC ADVANCES | 2013年 / 3卷 / 34期

关键词：

CU-3(BTC)(2); SELECTIVITY; FABRICATION;

D O I：

10.1039/c3ra22733b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A uniquely microstructured membrane, a metal-organic framework (MOF) layer within the porous support, was prepared by a counter-diffusion method. The MOF-based membrane prepared from the copper benzene tricarboxylate (Cu-BTC), one of the MOFs, exhibited excellent gas perm-separation properties with an ideal H-2/CH4 selectivity of 153.

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页码：14233 / 14236

页数：4

相关论文

共 18 条

[1] Zeolite membranes -: state of their development and perspective [J].

Caro, J ;

Noack, M ;

Kölsch, P ;

Schäfer, R .

MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 38 (01) :3-24

[2] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[3] HKUST-1 membranes on porous supports using secondary growth [J].

Guerrero, Victor Varela ;

Yoo, Yeonshick ;

McCarthy, Michael C. ;

Jeong, Hae-Kwon .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (19) :3938-3943

[4] Roles of transients and nucleation in film deposition within a support [J].

Gummalla, M ;

Tsapatsis, M ;

Watkins, JJ ;

Vlachos, DG .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (07) :1321-1328

[5] "Twin Copper Source" Growth of Metal-Organic Framework Membrane: Cu3(BTC)2 with High Permeability and Selectivity for Recycling H2 [J].

Guo, Hailing ;

Zhu, Guangshan ;

Hewitt, Ian J. ;

Qiu, Shilun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1646-+

[6] Metal-organic framework membranes fabricated via reactive seeding [J].

Hu, Yaoxin ;

Dong, Xueliang ;

Nan, Jiangpu ;

Jin, Wanqin ;

Ren, Xiaoming ;

Xu, Nanping ;

Lee, Young Moo .

CHEMICAL COMMUNICATIONS, 2011, 47 (02) :737-739

[7] Steam-Stable Zeolitic Imidazolate Framework ZIF-90 Membrane with Hydrogen Selectivity through Covalent Functionalization [J].

Huang, Aisheng ;

Dou, Wei ;

Caro, Juergen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (44) :15562-15564

[8] Zeolitic imidazolate framework ZIF-7 based molecular sieve membrane for hydrogen separation [J].

Li, Yanshuo ;

Liang, Fangyi ;

Bux, Helge ;

Yang, Weishen ;

Caro, Juergen .

JOURNAL OF MEMBRANE SCIENCE, 2010, 354 (1-2) :48-54

[9] Step-by-Step Seeding Procedure for Preparing HKUST-1 Membrane on Porous α-Alumina Support [J].

Nan, Jiangpu ;

Dong, Xueliang ;

Wang, Wenjin ;

Jin, Wanqin ;

Xu, Nanping .

LANGMUIR, 2011, 27 (08) :4309-4312

[10] Microporous Metal Organic Framework Membrane on Porous Support Using the Seeded Growth Method [J].

Ranjan, Rajiv ;

Tsapatsis, Michael .

CHEMISTRY OF MATERIALS, 2009, 21 (20) :4920-4924