Selective oxidation of organic compounds - Sustainable catalytic reactions with oxygen and without transition metals?

被引:132
作者
Lenoir, Dieter [1 ]
机构
[1] GSF Forschungszentrum Umwelt & Gesundheit, Inst Okol Chem, D-85778 Neuherberg, Germany
关键词
dioxygen; environmental chemistry; oxidation; pollutants; sustainability;
D O I
10.1002/anie.200502702
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Going without: Alcohols can be oxidized with oxygen and without transition-metal complexes (see scheme; TEMPO = 2,2,6,6-tetramethylpiperidine-N-oxide). Conventional methods are compared with new catalytic variants developed for this reaction and for the complete oxidation of pollutants with regard to sustainability. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3206 / 3210
页数:5
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