Base-free hydrogen generation from methanol using a bi-catalytic system

被引：115

作者：

Monney, Angele

Barsch, Enrico

Sponholz, Peter

Junge, Henrik

Ludwig, Ralf

Beller, Matthias ^{[1
]}

机构：

[1] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 06期

关键词：

FORMIC-ACID; RUTHENIUM COMPLEXES; DEHYDROGENATION; ECONOMY; ACCEPTORLESS; LIGANDS; ETHANOL;

D O I：

10.1039/c3cc47306f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bi-catalytic system, in which Ru-MACHO-BH and Ru(H)(2)(dppe)(2) interact in a synergistic manner, was developed for the base-free dehydrogenation of methanol. A total TON > 4200 was obtained with only trace amounts of CO contamination (<8 ppm) in the produced gas.

引用

收藏

页码：707 / 709

页数：3

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