Vinyl C-H activation reactions of vinyl esters mediated by B(C6F5)3

被引：13

作者：

Dash, AK ^{[1
]}

Jordan, RF ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 05期

关键词：

D O I：

10.1021/om010515e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

B(C6F5)(3) reacts with simple vinyl esters by electrophilic addition to the C=C bond and subsequent proton transfer and elimination of C6F5H to yield the chelated vinylborane products (C6F5)(2)B{kappa(2)-CH=CHOC-(=O)R} (R = Me, Ph).

引用

页码：777 / 779

页数：3

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