How high the spin? Allowed and forbidden spin states in transition-metal chemistry

被引：47

作者：

Alvarez, Santiago

Cirera, Jordi

机构：

[1] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain

[2] Univ Barcelona, Ctr Especial Recerca & Quim, Barcelona 08028, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 19期

关键词：

coordination compounds; ligand field theory; molecular orbital theory; spin states; transition metals;

D O I：

10.1002/anie.200503492

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) How high is high and how low is low? With respect to transition-metal complexes of different coordination numbers and stereochemistry, high-, low-, and intermediate-spin states may mean different things. The hybridization of the d orbitals, similar to the deformation of a balloon subjected to pressure (see picture), provides a rationale for the splitting of the d manifold and, hence, for the allowed spin states in a given complex. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3012 / 3020

页数：9

共 96 条

[21] Hydrogenolysis of [PhBP3]FeN-p-tolyl:: Probing the reactivity of an iron imide with H2
Brown, SD
Peters, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (14) : 4538 - 4539
[22] A low-spin d5 iron imide:: Nitrene capture by low-coordinate iron(I) provides the 4-coordinate Fe(III) complex [PhB(CH2PPh2)3]FeN-p-tolyl
Brown, SD
Betley, TA
Peters, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (02) : 322 - 323
[23] Buschmann WE, 1998, ANGEW CHEM INT EDIT, V37, P781, DOI 10.1002/(SICI)1521-3773(19980403)37:6<781::AID-ANIE781>3.0.CO
[24] 2-Z
[25] BUSCHMANN WE, 1998, ANGEW CHEM, V110, P813
[26] Homoleptic cobalt and copper phenolate A2[M(OAr)4] compounds:: The effect of phenoxide fluorination
Buzzeo, MC
Iqbal, AH
Long, CM
Millar, D
Patel, S
Pellow, MA
Saddoughi, SA
Smenton, AL
Turner, JFC
Wadhawan, JD
Compton, RG
Golen, JA
Rheingold, AL
Doerrer, LH
[J]. INORGANIC CHEMISTRY, 2004, 43 (24) : 7709 - 7725
[27] SYNTHESIS, CHARACTERIZATION, AND ELECTRON-TRANSFER REACTIVITY OF NORBORNYL COMPLEXES OF COBALT IN UNUSUALLY HIGH OXIDATION-STATES
BYRNE, EK
THEOPOLD, KH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) : 3887 - 3896
[28] Mapping the stereochemistry and symmetry of tetracoordinate transition-metal complexes
Cirera, J
Alemany, P
Alvarez, S
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) : 190 - 207
[29] Cotton F. A., 1990, Chemical Applications of Group Theory
[30] Damhus T., 2005, NOMENCLATURE INORGAN

← 1 2 3 4 5 6 7 8 9 10 →