Hexacyanometalates as templates for heteropolynuclear complexes and molecular magnets: Synthesis and crystal structure of [Fe{(CN)Cu(tpa)}(6)][ClO4](8)center dot 3H(2)O, [tpa equals tris(2-pyridylmethyl)amine]

被引：81

作者：

Parker, RJ

Hockless, DCR

Moubaraki, B

Murray, KS

Spiccia, L

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 24期

关键词：

D O I：

10.1039/cc9960002789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Fe(CN)(6)](3-) with [Cu(tpa)(OH2)](2+) produces a bimetallic heptanuclear complex, [Fe{(CN)Cu(tpa)}(6)]-[ClO4](8) . 3H(2)O, which is characterised by single-crystal X-ray diffraction and shown to consist of an iron(II) centre connected by cyano bridges to six copper(II) centres forming spherical units of [Fe{(CN)Cu(tpa)}(6)](8+).

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页码：2789 / 2790

页数：2

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